Quaternary Ammonium-Containing Polyelectrolyte Brush Particles for Removal of Perrhenate Anion From Water: Effect of...

Radioactive pertechnetate (TcO₄ ^-) from the nuclear fuel cycle presents a severe risk to the environment due to its large solubility in water and non-complexing nature. By utilizing the chaotropic properties of TcO₄ ^- and its nonradioactive surrogate perrhenate (ReO₄ ^-) and the principle of chaotropic interactions, a series of quaternary ammonium-containing polyelectrolyte brush-grafted silica particles are designed and applied to remove ReO₄ ^- from water. These cationic hairy particles (HPs) are synthesized by surface-initiated atom transfer radical polymerization of 2-(N,N-dimethylamino)ethyl methacrylate and subsequent quaternization with various halogen compounds. Dynamic light scattering (DLS) studies showed that the HPs with sufficiently long N-alkyl and N-benzyl substituents underwent sharp size reduction transitions in water when titrated with a KReO₄ solution, indicating strong chaotropic interactions between the brushes and ReO₄ ^-. All the HPs exhibited fast adsorption kinetics; the HPs with longer N-alkyl and N-benzyl substituents showed higher capabilities of removing ReO₄ ^- than those with shorter N-alkyls. Moreover, the brush particles with longer N-substituents displayed a significantly stronger ability in selective adsorption of ReO₄ ^- than the particles with shorter N-substituents in the presence of competing anions, such as F^-, Cl^-, NO₃ ^-, and SO₄ ^2-. This work opens a new avenue to design high-performance adsorbent materials for TcO₄ ^- and ReO₄ ^-.