Self-Assembled Sandwich-like Mixed Matrix Membrane of Defective Zr-MOF for Efficient Gas Separation

Membrane technology has been widely used in industrial CO₂ capturing, gas purification and gas separation, arousing attention due to its advantages of high efficiency, energy saving and environmental protection. In the context of reducing global carbon emissions and combating climate change, it is particularly important to capture and separate greenhouse gasses such as CO₂. Zr-MOF can be used as a multi-dimensional modification on the polymer membrane to prepare self-assembled MOF-based mixed matrix membranes (MMMs), aiming at the problem of weak adhesion or bonding force between the separation layer and the porous carrier. When defective UiO-66 is applied to PVDF membrane as a functional layer, the CO₂ separation performance of the PVDF membrane is significantly improved. TUT-UiO-3-TTN@PVDF has a CO₂ permeation flux of 14,294 GPU and a selectivity of 27 for CO₂/N₂ and 18 for CO₂/CH₄, respectively. The CO₂ permeability and selectivity of the membrane exhibited change after 40 h of continuous operation, significantly improving the gas separation performance and showing exceptional stability for large-scale applications.