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Related Concept Videos

Molecules with Multiple Chiral Centers02:25

Molecules with Multiple Chiral Centers

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Molecules that possess multiple chiral centers can afford a large number of stereoisomers. For instance, while some molecules like 2-butanol have one chiral center, defined as a tetrahedral carbon atom with four different substituents attached, several molecules like butane-2,3-diol have multiple chiral centers. A simple formula to predict the number of stereoisomers possible for a molecule with n chiral centers is 2n. However, there can be a lower number where some of the stereoisomers are...
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Chirality02:25

Chirality

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Chirality is a term that describes the lack of mirror symmetry in an object. In other words, chiral objects cannot be superposed on their mirror images. For example, our feet are chiral, as the mirror image of the left foot, the right foot, cannot be superposed on the left foot.
Chiral objects exhibit a sense of handedness when they interact with another chiral object. For example, our left foot can only fit in the left shoe and not in the right shoe. Achiral objects — objects that have...
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Prochirality02:05

Prochirality

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The concept of prochirality leads to the nomenclature of the individual faces of a molecule and plays a crucial role in the enantioselective reaction. It is a concept where two or more achiral molecules react to produce chiral products. A typical process is the reaction of an achiral ketone to generate a chiral alcohol. Here, the achiral reactant reacts with an achiral reducing agent, sodium borohydride, to generate an equimolar mixture of the chiral enantiomers of the product. For example, an...
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Chirality in Nature02:30

Chirality in Nature

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Chirality is the most intriguing yet essential facet of nature, governing life’s biochemical processes and precision. It can be observed from a snail shell pattern in a macroscopic world to an amino acid, the minutest building block of life. Most of the snails around the world have right-coiled shells because of the intrinsic chirality in their genes. All the amino acids present in the human body exist in an enantiomerically pure state, except for glycine - the sole achiral amino acid.
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Stereoisomerism02:52

Stereoisomerism

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Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula.
Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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Chirality at Nitrogen, Phosphorus, and Sulfur02:30

Chirality at Nitrogen, Phosphorus, and Sulfur

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Chirality is most prevalent in carbon-based tetrahedral compounds, but this important facet of molecular symmetry extends to sp3-hybridized nitrogen, phosphorus and sulfur centers, including trivalent molecules with lone pairs. Here, the lone pair behaves as a functional group in addition to the other three substituents to form an analogous tetrahedral center that can be chiral.
A consequence of chirality is the need for enantiomeric resolution. While this is theoretically possible for all...
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Updated: May 26, 2025

An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation
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An Electrochemical Cholesteric Liquid Crystalline Device for Quick and Low-Voltage Color Modulation

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Chiral structural color from microdomes.

Xintao Lai1,2, Tongyu Li3, Xiaoyu Hou2

  • 1Key Laboratory of Bio-Inspired Materials and Interface Science, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, People's Republic of China.

Proceedings of the National Academy of Sciences of the United States of America
|February 25, 2025
PubMed
Summary
This summary is machine-generated.

Common polymer microdomes create tunable chiral structural colors for advanced optical security. These microdomes offer high-capacity information encryption and anti-counterfeiting solutions, including secure identity authentication via contact lenses.

Keywords:
anti-counterfeitingchiralityencryptionstructural color

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Area of Science:

  • Materials Science
  • Optics
  • Nanotechnology

Background:

  • Artificial chiral-structural-color materials offer high-dimensional information storage and optical security.
  • Current materials face limitations in composition, nanostructure fabrication, and polarization modulation.

Purpose of the Study:

  • To develop novel chiral structural color materials with tunable properties.
  • To explore applications in high-capacity information encryption and anti-counterfeiting.

Main Methods:

  • Fabrication of microdome patterns using common polymers via ordinary printing techniques.
  • Characterization of broadband tunability and multiple polarization-modulated chirality.
  • Development of multidimensional tunable structural color displays.

Main Results:

  • Microdomes exhibit tunable chiral structural colors with broadband tunability and multiple polarization-modulated chirality.
  • Easily fabricated microdome patterns display inhomogeneous spatial distributions of full polarization states and customizable colors.
  • Achieved high-capacity information encryption and developed contact lenses with 2^32 distinct cryptograms for identity authentication.

Conclusions:

  • Chiral-structural-color microdomes (CSCMs) present a viable approach for advanced optical security and anti-counterfeiting.
  • The developed CSCMs enable high-capacity information encryption and secure identity authentication.
  • This technology holds significant potential for secure information storage and authentication applications.