Related Experiment Video
Updated: May 26, 2025

Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides Mediated by Ni/Zn Complexes
Published on: November 21, 2017
Biphenylene Coordination and Ring-Opening by Alkali-Metal Nickelates
Andryj M Borys1, Aurore E F Denjean2, Luca Vedani1
1Departement für Chemie, Biochemie und Pharmazie, Universität Bern, Freiestrasse 3, Bern, 3012, Switzerland.
Abstract:
The pre-coordination of substrates to heterobimetallic complexes plays a key role in facilitating challenging bond activations and catalytic reactions. Herein, we report a family of low-valent phenyl-alkali-metal nickelates containing a η4-coordinated biphenylene ligand and demonstrate how the coordination and solvation preferences of the alkali-metal cation (Li, Na, or K) influence the rate of C─C bond oxidative addition at nickel through combined structural, spectroscopic and computational studies. The rate of C─C bond cleavage can be further manipulated by replacing the two phenyl-carbanionic ligands with a cyclic 2,2'-biphenyl scaffold, which affords thermally stable and symmetric spirocyclic nickelates upon ring-opening.
More Related Videos
12:19Photogeneration of N-Heterocyclic Carbenes: Application in Photoinduced Ring-Opening Metathesis Polymerization
Published on: November 29, 2018
19:58Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
Published on: July 30, 2017
Related Concept Videos
Metal-Ligand Bonds
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
Base-Catalyzed Ring-Opening of Epoxides
Valence Bond Theory
Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)
Acid-Catalyzed Ring-Opening of Epoxides
Structural Isomerism
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
Linkage isomers occur when the coordination compound contains a ligand that can bind to the transition metal center through two different atoms. For example, the CN− ligand can bind through the carbon atom or through the nitrogen atom. Similarly, SCN− can...