Functionalization of Nanomaterials for Energy Storage and Hydrogen Production Applications

This review article provides a comprehensive overview of the pivotal role that nanomaterials, particularly graphene and its derivatives, play in advancing hydrogen energy technologies, with a focus on storage, production, and transport. As the quest for sustainable energy solutions intensifies, the use of nanoscale materials to store hydrogen in solid form emerges as a promising strategy toward mitigate challenges related to traditional storage methods. We begin by summarizing standard methods for producing modified graphene derivatives at the nanoscale and their impact on structural characteristics and properties. The article highlights recent advancements in hydrogen storage capacities achieved through innovative nanocomposite architectures, for example, multi-level porous graphene structures containing embedded nickel particles at nanoscale dimensions. The discussion covers the distinctive characteristics of these nanomaterials, particularly their expansive surface area and the hydrogen spillover effect, which enhance their effectiveness in energy storage applications, including supercapacitors and batteries. In addition to storage capabilities, this review explores the role of nanomaterials as efficient catalysts in the hydrogen evolution reaction (HER), emphasizing the potential of metal oxides and other composites to boost hydrogen production. The integration of nanomaterials in hydrogen transport systems is also examined, showcasing innovations that enhance safety and efficiency. As we move toward a hydrogen economy, the review underscores the urgent need for continued research aimed at optimizing existing materials and developing novel nanostructured systems. Addressing the primary challenges and potential future directions, this article aims to serve as a roadmap to enable scientists and industry experts to maximize the capabilities of nanomaterials for transforming hydrogen-based energy systems, thus contributing significantly to global sustainability efforts.