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Reaction Behavior and Kinetic Model of Hydroisomerization and Hydroaromatization of Fluid Catalytic Cracking Gasoline
Haijun Zhong1,2,3, Xiwen Song1, Shuai He1
1Petrochemical Research Institute, PetroChina Company Limited, Beijing 102206, China.
Abstract:
The hydro-upgrading reaction behavior of model compound 1-hexene and FCC middle gasoline was investigated using a fixed-bed hydrogenation microreactor with a prepared La-Ni-Zn/H-ZSM-5 catalyst. The catalyst was prepared by wetness impregnation method, using hydrothermal treated H-ZSM-5 zeolite blended with alumina as the support, and La, Ni, Zn as the active metals. The reaction tests were carried out at 300-380 °C, 1.0 MPa, 1.5-3.0 h-1 (LSHV), and 300:1 v/v (H2/oil). Analyzing the changes in hydrocarbon components before and after hydro-upgrading elucidated the mechanistic pathways of olefin hydroisomerization and hydroaromatization. Based on these findings, a seven-lump kinetic model was established for the FCC middle gasoline hydro-upgrading process. Given the diversity and complexity of reaction products, they were grouped into seven lumps: normal paraffins, isoparaffins, linear olefins, branched olefins, cycloolefins, naphthenes, and aromatics. Kinetic parameters were estimated using the Levenberg-Marquardt algorithm and validated against experimental data. The results showed that the conversion of naphthenes to aromatics exhibited the highest activation energy and pre-exponential factor, resulting in the largest reaction rate increase within the 320-380 °C range. The model accurately predicted the product yields of FCC gasoline hydro-upgrading, with a relative error of less than 5%. These findings provide valuable guidance for the optimization, design, and operation of FCC gasoline hydro-upgrading units, as well as for catalyst development, with the aim of improving process efficiency and fuel quality.
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