Anharmonicity and vibrational Stark fields in phosphinic acid dimers

Manjusha Boda1, Arzoo1, G Naresh Patwari1

  • 1Department of Chemistry, Indian Institute of Technology Bombay, Mumbai 400076, India. naresh@chem.iitb.ac.in.

Summary

Phosphinic acid forms stable cyclic dimers through hydrogen bonding, stronger than carboxylic acids. This enhanced stability is linked to electric field effects on OH groups and significant anharmonicity.

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