Related Experiment Video
Updated: May 24, 2025

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
Published on: January 19, 2018
Tracking spin flip-flop dynamics of surface molecules with quantum dissipation theory
Xu Ding1,2, Jiaan Cao1, Xiao Zheng3,4
1Hefei National Research Center for Physical Sciences at the Microscale and Synergetic Innovation Center of Quantum Information and Quantum Physics, University of Science and Technology of China, Hefei, Anhui 230026, China.
Abstract:
The integration of scanning tunneling microscopy (STM) and electron spin resonance spectroscopy with voltage pulses is an emerging technique to probe the local spin dynamics of surface-adsorbed molecules. However, in experiments, the detection of real-time spin dynamics is severely hampered by the limited temporal resolution of STM electronics, and the associated theoretical investigations are still in their early stages due to various challenges in numerical simulations. In this work, we employ the highly accurate hierarchical equations of motion method to characterize the spin states and track the real-time coherent flip-flop spin dynamics in a surface-adsorbed hydrogenated Ti dimer. Our simulations accurately reproduce the experimental observations and reveal the influences of substrate and pulse duration on the spin decoherence process of the dimer. These achievements provide valuable insights into the coherent spin dynamics of surface-adsorbed molecules and set the stage for the application of surface-adsorbed molecular spins to quantum sensing, quantum information processing, and quantum computing.
Related Concept Videos
Atomic Nuclei: Types of Nuclear Relaxation
In spin–lattice or longitudinal relaxation, the excited spins exchange energy with the surrounding lattice as they return to the lower energy level. Among several mechanisms that contribute to spin–lattice relaxation, magnetic dipolar interactions are significant. Here, the excited nucleus transfers...
Spin–Spin Coupling Constant: Overview
Qualitatively, any spin plus-half nucleus polarizes the spins of its electrons to the minus-half state. Consequently, the paired electron in the hydrogen–carbon bond must...
¹H NMR: Interpreting Distorted and Overlapping Signals
As Δν decreases and the signals move closer, the doublets appear increasingly distorted. The intensities of the inner lines increase at the cost of those of the outer lines as the signals are...
Atomic Nuclei: Nuclear Relaxation Processes
Atomic Nuclei: Nuclear Spin State Overview
Atomic Nuclei: Nuclear Spin State Population Distribution

