Biopolymers to composite adsorbents for sulfate removal: From conventional to sustainable systems

Addressing elevated water salinity is a global water security issue listed among the UN's Sustainable Development Goals (UN-SDGs). Sulfate is a contributor to water salinity due to its high solubility and is a pollutant of increasing global concern. While various water treatment technologies are currently available, the high capital infrastructure and operational costs of such advanced methods have sustainability limits for their widespread adoption. By contrast, adsorption science and technology offers facile treatment and a sustainable mitigation strategy for the removal of oxyanions such as sulfate. A key challenge in adsorption science and technology relates to the molecular selective uptake of sulfate. This has catalysed significant effort towards achieving improved adsorption properties and the development of sustainable adsorbent technology. This review provides coverage of recent literature on synthetic adsorbents to current research on biosorbents that contain chitosan due to its multifunctional colloid and interface properties. The shift from conventional synthesis to green synthetic strategies are highlighted by the preparation of advanced biocomposite materials with unique sulfate adsorption properties. Diverse types of materials from inorganic minerals to polymer-based adsorbents (e.g., polycaprolactones, waste-based materials from fly ash, etc.) is described to highlight their sulfate adsorption properties. Specifically, chitosan and agricultural biomass waste in the form of lignocellulose materials are abundant and promising renewable platforms for the preparation of sulfate adsorbents. In particular, the adsorption properties of chitosan biocomposites are highlighted by its efficacy for adsorption-based remediation of sulfate oxyanions that reveal its promising utility as sulfate adsorbents with unique colloidal and interface properties.