Exploring Bio-Based Monomers in Emulsion and Miniemulsion Polymerization
Sara Mohebbi1, Robin A Hutchinson1, Michael F Cunningham1
1Department of Chemical Engineering, Queen's University, Kingston, Ontario, K7L 3N6, Canada.
Macromolecular Rapid Communications
|March 5, 2025
Summary
This review explores bio-based monomers for sustainable emulsion polymerization, offering greener alternatives to petroleum-based plastics. These renewable materials enhance eco-friendly polymer production and applications.
Area of Science:
- Polymer Chemistry
- Materials Science
- Green Chemistry
Background:
- Polymer synthesis increasingly prioritizes sustainability, seeking alternatives to nonrenewable resources.
- Emulsion polymerization offers an environmentally friendly approach using water as a dispersant.
- Incorporating renewable, bio-based materials into polymerization enhances process sustainability.
Purpose of the Study:
- To review recent advancements in bio-based monomers for emulsion and miniemulsion polymerization.
- To highlight sustainable alternatives to petroleum-based monomers.
- To examine the properties and applications of polymers derived from bio-based monomers.
Main Methods:
- Review of scientific literature on bio-based monomers in (mini)emulsion polymerization.
- Analysis of monomer categories: vegetable oils, lignin derivatives, terpenes, proteins, and carbohydrates.
- Examination of polymerization processes, product properties, and applications.
Main Results:
- Identification of key bio-based monomers as viable replacements for petroleum-derived counterparts.
- Demonstration of successful incorporation of these monomers into emulsion and miniemulsion systems.
- Characterization of resulting polymers, showcasing diverse properties and applications.
Conclusions:
- Bio-based monomers represent a significant advancement in sustainable polymer synthesis.
- Emulsion and miniemulsion polymerization are effective methods for utilizing these renewable resources.
- The use of bio-based monomers paves the way for eco-friendlier polymers across various applications.
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