Constructing Hydrophilic Polymer Membranes with Microporosity for Aqueous Redox Flow Batteries

Ion selective membranes (ISMs) are key components of aqueous redox flow batteries (ARFBs), and their property in selective ion transport largely determines the energy storage efficiency of ARFBs. Traditional ISMs are based on microphase-separated structures and have been advanced for many years, but most of them show poor performance as membrane separators in ARFBs due to their conductivity-selectivity. In recent years, using confined micropores instead of dense hydrophilic regions as ion channels has been demonstrated to effectively break this tradeoff. We here summarize the synthetic strategies for constructing hydrophilic polymer membranes with microporosity and highlight the performance of some typical microporous ISMs in ARFBs. We also propose fundamental issues that remain to be addressed for the further development of ISMs.