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1,2-Bis-Triazenylarenes Enable Vicinal Sandmeyer-Type Reactions

Christeena Mathew1, Anastasia Yu Gitlina1, Carl Thomas Bormann1

  • 1Institut des Sciences et Ingénierie Chimiques, Ecole Polytechnique, Fédérale de Lausanne (EPFL), Lausanne, 1015, Switzerland.

Angewandte Chemie (International Ed. in English)
|March 7, 2025
PubMed
Summary

This study introduces 1,2-bis-triazenylarenes as effective reagents for vicinal substitution reactions on arenes, overcoming limitations of traditional methods. These compounds allow sequential nucleophilic substitution, enabling diverse arene functionalization.

Keywords:
CatalysisCycloadditionSandmeyer reactionSubstitution reactionTriazenes

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