Related Experiment Video
Updated: May 23, 2025

Tuning Oxide Properties by Oxygen Vacancy Control During Growth and Annealing
Published on: June 9, 2023
Doping dependence of the dipolar correlation length scale in metallic SrTiO3
Benoît Fauqué1, Shan Jiang2, Tom Fennell3
1JEIP (USR 3573 CNRS), Collège de France, Paris, France. benoit.fauque@espci.fr.
Abstract:
Superconducting domes, ubiquitous across a variety of quantum materials, are often understood as a window in which pairing is favored, opened by the fluctuations of competing orders. Yet, the understanding of how such a window closes is missing. Here, we show that inelastic neutron scattering, by quantifying a length scale associated with the dipoles correlation, ℓ0, addresses this issue. We find that, within the experimental precision, the end of the superconducting dome coincides with the end of a highly polarizable state (in which ℓ0 is longer than the interatomic distance). Thus, the superconducting dome is driven by the competition between the increase in the density of states and the inevitable collapse of the quantum paraelectric phase. This is compatible with a crucial role played by the soft ferroelectric mode in driving superconductivity. Such a scenario may also be at work in other quantum paraelectric materials, either bulk or at interfaces.
Related Concept Videos
Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
Theory of Metallic Conduction
In this theory, Newton's second law of motion is used to determine the acceleration of an electron in the presence of an applied electric field. Then, its velocity is expressed via this acceleration.
An electron moves through the crystal, containing positive ions,...
Van der Waals Interactions
Valence Bond Theory
Metallic Solids
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....

