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Published on: May 2, 2014
Photothermal enhanced bifunctional catalyst for overall water splitting with phosphide heterojunction Fe2P-CoMoP
1School of Energy Materials and Chemical Engineering, Hefei University, Hefei 230601, PR China; Key Laboratory of Materials and Technologies for Advanced Batteries, Hefei University, Hefei 230601, PR China.
Abstract:
The development of cost-effective bifunctional electrocatalysts remains a great challenge. In this work, high-performance Fe2P-CoMoP/NF catalysts were prepared using the strategy of constructing phosphide heterostructures with localized photothermal effect. At 10 mA·cm-2, the HER overpotential of Fe2P-CoMoP/NF is 30.8 mV and the OER overpotential is 180.9 mV. Compared to Fe2P/NF and CoMoP/NF, the higher content of oxygen vacancies in the phosphorylated heterostructure Fe2P-CoMoP/NF has the potential to enhance intrinsic activity and improve the photothermal effect. With the assistance of localized photothermal effect, the HER (η100 = 72.7 mV) and OER (η100 = 252.3 mV) overpotentials of Fe2P-CoMoP/NF decreased by 35.8 % and 9.9 %, which were more significant than those of CoMoP/NF and Fe2P/NF. Meanwhile, the Fe2P-CoMoP/NF catalyst has excellent stability, maintaining 96 % at -500 mA·cm-2 and 94 % at 300 mA·cm-2 after 100 h. In addition, overall water splitting can be carried out using solar panels with a voltage of 1.42 V, which shows its potential for application in combination with sustainable energy sources.
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