N-Oxide Zwitterionic-Based Antifouling Loose Nanofiltration Membranes with Superior Water Permeance and Effective...

Loose nanofiltration (LNF) membranes with high permeance and separation selectivity are highly desired for the effective separation of organic dyes and inorganic salts. Herein, a novel polyamide LNF membrane was fabricated using zwitterionic amine reactant trimethylamine N-oxide-based polyethylenimine (TPEI) and trimesoyl chloride (TMC) via interfacial polymerization (IP). A thin, loose, and smooth polyamide layer was formed due to the low diffusion rate and modified chemical structure of TPEI. The optimized membrane (NF-TPEI) exhibited an extremely high water permeance of 213.0 L m^-2 h^-1 bar^-1, accompanied by outstanding dye rejections of Congo Red (99.8%), Coomassie Brilliant Blue R250 (99.5%), and Evans Blue (99.9%). Meanwhile, the membrane possessed low rejections (<7.0%) of inorganic salts (Na₂SO₄, MgSO₄, MgCl_2, and NaCl). Additionally, the NF-TPEI membrane exhibited outstanding antifouling performance, achieving a superior recovery ratio of 96.0 and 98.1% after the filtration of humic acid and sodium alginate solution, respectively. Compared to the commercial NF270 membrane, the NF-TPEI membrane exhibited significantly improved separation performance in terms of permeance and fouling resistance, which provided more possibilities for high-performance LNF membranes toward the treatment of wastewater with organic contaminants.