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Modified bentonite @ microwave for Mn(VII) removal with a simulation study.
Hend S Abu Salem1, Safaa S Hassan2, Fatma A Refay3
1Geology Department, Faculty of Science, Cairo University, Giza, 12613, Egypt. hendsaeed@cu.edu.eg.
Microwave treatment enhances natural bentonite's ability to remove manganese (VII) ions from water. This modified bentonite shows improved adsorption capacity due to increased surface area and altered pore structure.
Area of Science:
- Environmental Science
- Materials Science
- Water Treatment
Background:
- Polluted water poses environmental and health risks.
- Manganese (VII) ions are a significant water contaminant.
- Natural bentonite is a cost-effective adsorbent.
Purpose of the Study:
- To investigate the effect of microwave treatment on bentonite structure.
- To evaluate the adsorption capacity of microwave-treated bentonite for Mn(VII) ions.
- To understand the adsorption mechanism of Mn(VII) on modified bentonite.
Main Methods:
- Characterization of natural and microwave-treated bentonite using XRD, EDX, FTIR, and BET analysis.
- Determination of pore size distribution and surface area.
- Adsorption experiments to assess Mn(VII) removal efficiency.
Main Results:
- Microwave treatment altered bentonite structure, creating new nucleation centers.
- The specific surface area increased from 277.624 to 327.085 m²/g after microwave treatment.
- Adsorption capacity for Mn(VII) ions increased by approximately 18.0% compared to untreated bentonite.
Conclusions:
- Microwave treatment is an effective method to enhance bentonite's adsorption properties.
- Modified bentonite shows superior performance in removing Mn(VII) ions from polluted water.
- This study highlights the potential of engineered natural adsorbents for water remediation.
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