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Rb7PbY2(B5O10)3: A Noncentrosymmetric Rare-Earth Borate Nonlinear Optical Crystal with [B5O10] Unit
Xinyu Gao1,2, Qingyu Liu1,2, Zhihua Yang1,2
1Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments; Xinjiang Key Laboratory of Functional Crystal Materials; Xinjiang Technical Institute of Physics & Chemistry, CAS, 40-1 South Beijing Road, Urumqi 830011, China.
Abstract:
For ultraviolet (UV) nonlinear optical (NLO) crystals, three fundamental parameters are essential: the absorption edge, the NLO coefficient, and the shortest wavelength for second harmonic generation (SHG) phase matching (PM). In this study, a rare-earth borate, Rb7PbY2(B5O10)3, was synthesized via chemical cosubstitution using a high-temperature melt method. Rb7PbY2(B5O10)3 has been found to crystallize with a noncentrosymmetric (NCS) space group and has an SHG intensity of 1.3 times KDP and a UV cutoff edge of less than 300 nm. These properties indicate that Rb7PbY2(B5O10)3 exhibits significant potential as an NLO material.
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