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Updated: May 22, 2025

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
1D Metal Mediated Hydrogen Bonded Rods with Rich Phenyl Groups for Highly Efficient Oil Removal
Xue Yin1,2, Jia Chen1, Xin Li1
1CAS Key Laboratory of Chemistry of Northwestern Plant Resources and Key Laboratory for Natural Medicine of Gansu Province, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, 730000, China.
Abstract:
In this work, a novel 1D metal-mediated hydrogen-bonded framework with rich phenyl groups is first synthesized employing Co2+ and dibenzoylmethane (DBM) as precursors, which are named HOF-Co-DBM and exhibit exceptional thermal stability, excellent chemical durability, and super hydrophobicity. These distinctive properties can be attributed to the high density, robust Co─O coordination bonds, and the presence of strong hydrogen bonds (O─H─O─C) characterized by short bond distances, which contribute to its close-packed structure. Additionally, the benzene rings flanking the framework further enhance its hydrophobicity. The HOF-Co-DBM is subsequently integrated into a polyurethane (PU) sponge, resulting in exceptional oil removal performance. This study demonstrates the potential for preparing ultra-stable and superhydrophobic hydrogen-bonded organic framework materials with a wide range of applications.
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