Related Experiment Video
Updated: May 21, 2025
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Compression of Molybdenum Blue Polyoxometalate Cluster Rings
Vishal Lakhanpal1, Melanie Guillén-Soler1, Laia Vilà-Nadal1
1School of Chemistry, University of Glasgow, University Avenue, Glasgow G12 8QQ, United Kingdom.
Abstract:
The self-assembly of polyoxometalate (POM) clusters remains challenging because they heavily depend on highly sensitive synthetic conditions that produce a vast library of potential building blocks and subunits such that explicit control is hard. This work reports new strategies to construct compressed molybdenum blue (MB) type cluster rings with a new range of giant MB POM clusters {Mo54}, {Mo58}, {Mo85}, and {Mo108}. These MB clusters prove the limits of the ring structure archetype, showing that it is possible to compress the ring by 100 metal atoms from 154 to 54 yet keep the electronic structure and ring shape. These structures comprise distorted pentagonal building blocks. The compression of the ring is achieved by using a {Mo3S} unit and {Mo5} bridging units. The {Mo85} and {Mo108} clusters exhibit a unique closed architecture, and redox studies demonstrate the reduced nature of these clusters.
Related Concept Videos
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
01:16Olefin Metathesis Polymerization: Ring-Opening Metathesis Polymerization (ROMP)
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...