Related Experiment Video
Updated: May 21, 2025

An Analog Macroscopic Technique for Studying Molecular Hydrodynamic Processes in Dense Gases and Liquids
Published on: December 4, 2017
Bridging Freidlin-Wentzell large deviations theory and stochastic thermodynamics
Davide Santolin1, Nahuel Freitas2, Massimiliano Esposito3
1University of Padova, Department of Physics and Astronomy, Via Marzolo 8, I-35131 Padova, Italy.
Abstract:
For overdamped Langevin systems subjected to weak thermal noise and nonconservative forces, we establish a connection between Freidlin-Wentzell large deviations theory and stochastic thermodynamics. First, we derive a series expansion of the quasipotential around the detailed-balance solution, that is, the system's free energy, and identify the conditions for the linear response regime to hold, even far from equilibrium. Second, we prove that the escape rate from dissipative fixed points of the macroscopic dynamics is bounded by the entropy production of trajectories that relax into and escape from the attractors. These results provide the foundation to study the nonequilibrium thermodynamics of dissipative metastable states.
Related Concept Videos
Entropy
Third Law of Thermodynamics
Path Between Thermodynamics States
Statements of the Second Law of Thermodynamics
Entropy Change in Reversible Processes
The statement can be further generalized to prove that entropy is a state function. Take a cyclic process between any two points on a p-V diagram.
Thermal expansion and Thermal stress: Problem Solving
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in...

