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Updated: May 21, 2025
Imine Metathesis by Silica-Supported Catalysts Using the Methodology of Surface Organometallic Chemistry
Published on: October 18, 2019
Hydroformylation over Zeolite Catalysts with Solvophobic Micropores
Yuexin Wu1,2, Zhiqiang Liu3, Hai Wang1
1Key Lab of Biomass Chemical Engineering of Ministry of Education and College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, China.
Abstract:
Traditional gas-liquid-solid triphase reactions are often limited by gas solubility and diffusion in the liquid phase. We reported that a solvophobic catalyst with gas-filled micropores could enrich enormous amounts of gas molecules to accelerate Rh-catalyzed hydroformylation. This reaction used siliceous MFI zeolite fixed Rh nanoparticles in a mesitylene solvent. Owing to the shape selectivity, zeolite micropores prevent mesitylene from wetting the solid, allowing the rapid transport and efficient enrichment of gaseous reactants. This catalyst catalyzed ethylene hydroformylation with a propanal production rate significantly higher than those of the generally supported catalysts.
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