Related Experiment Video
Updated: May 21, 2025
Tuning the Acidity of Pt/ CNTs Catalysts for Hydrodeoxygenation of Diphenyl Ether
Published on: August 17, 2019
Green Catalysis: Water as a Sustainable Medium in Organocatalyzed Reactions
Anfal Fatima1, Anam Shahzadi1, Adnan Majeed1
1Department of Chemistry, University of Agriculture Faisalabad, Faisalabad 38000, Pakistan.
Abstract:
The use of organocatalysts has increased significantly in recent years due to their tremendous applications in green solvents. Thus, using water as a solvent has evolved as a critical factor. Organocatalysts are efficient and sustainable agents for promoting chemical reactions in water. The literature has been extensively reviewed, and the use of various organocatalysts for three fundamental C-C bond-forming processes─the Aldol, Michael, and Mannich reactions in aqueous media─have been compiled in this study. Organocatalysts can overcome the limitations of conventional organic solvents by achieving high reaction rates and regioselectivity in water. This Review highlights the advantages of organocatalysts in aqueous media for these key reactions. It discusses the principles behind designing effective organocatalysts, focusing on their impact on selectivity, sustainability, and reaction efficiency. This study also summarizes the most significant advancements in sustainable organic reactions over the past decade.
More Related Videos
05:34Efficient Synthesis of Polyfunctionalized Benzenes in Water via Persulfate-promoted Benzannulation of α,β-Unsaturated Compounds and Alkynes
Published on: December 16, 2019
10:39Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Related Concept Videos
02:50Catalysis
02:34Regioselectivity and Stereochemistry of Acid-Catalyzed Hydration
02:17Reduction of Alkenes: Asymmetric Catalytic Hydrogenation
The metal catalyst used can be either heterogeneous or homogeneous. When hydrogenation of an alkene generates a chiral center, a pair of enantiomeric products is expected to form. However, an enantiomeric excess of one of the products can be facilitated using an enantioselective reaction or an...
02:15Preparation of Alcohols via Addition Reactions
The acid-catalyzed addition of water to the double bond of alkenes is a large-scale industrial method used to synthesize low-molecular-weight alcohols. An acidic atmosphere is required to allow the hydrogen in the water molecule to act as an electrophile and attack the double bond in an alkene. The addition of a proton to the double bond creates a carbocation intermediate. The proton preferentially bonds to the less substituted end of the double bond to create a more stable carbocation...
02:45Acid-Catalyzed Hydration of Alkenes
01:20Aldehydes and Ketones with Water: Hydrate Formation
The formation of hydrates is a reversible reaction. Hydrate formation is influenced by steric and electronic factors accompanying the alkyl substituents on the carbonyl group: The rate of hydrate formation increases with a decrease in the number of alkyl groups attached to the carbonyl carbon. Hence,...