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Coordination isomerism in dioxophosphorane cyanides

Ayu Afiqah Nasrullah1,2, Edgar Zander1, Fabian Dankert3

  • 1Leibniz Institut für Katalyse e.V. (LIKAT) A.-Einstein-Str. 29a 18059 Rostock Germany christian.hering-junghans@catalysis.de eszter.barath@catalysis.de.

Chemical Science
|March 24, 2025
PubMed

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Structural Isomerism02:34

Structural Isomerism

Isomerism in Complexes
Isomers are different chemical species that have the same chemical formula. Structural isomerism of coordination compounds can be divided into two subcategories, the linkage isomers and coordination-sphere isomers.
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Stereoisomerism

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Transition metal complexes often exist as geometric isomers, in which the same atoms are connected through the same types of bonds but with differences in their orientation in space. Coordination complexes with two different ligands in the cis and trans positions from a ligand of interest form isomers. For example, the octahedral [Co(NH3)4Cl2]+ ion has two isomers (Figure 1) In the cis...
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