Versatile Gas-Transfer Membrane in Water and Wastewater Treatment: Principles, Opportunities, and Challenges

Technologies using liquid-transfer membranes, such as microfiltration, ultrafiltration, and reverse osmosis, have been widely applied in water and wastewater treatment. In the last few decades, gas-transfer membranes have been introduced in various fields to facilitate mass transfer, in which gaseous compounds permeate through membrane pores driven by gradients in chemical concentration or potential. A notable knowledge gap exists among researchers working on these emerging gas-transfer membranes as they approach this subject from different angles and areas of expertise (e.g., material science versus microbiology). This review explores the versatile applications of gas-transfer membranes in water and wastewater treatment, categorizing them into three primary types according to the function of membranes: water vapor transferring, gaseous reactant supplying, and gaseous compound extraction. For each type, the principles, evolution, and potential for further development were elaborated. Moreover, this review highlights the potential knowledge transfer between different fields, as insights from one type of gas-transfer membrane could potentially benefit another. Despite their technical innovations, these processes still face challenges in practical operation, such as membrane fouling and wetting. We advocate for research focusing on more practical and sustainable membranes and careful consideration of these emerging membrane technologies in specific scenarios. The current practicality and maturity of these emerging processes in water and wastewater treatment are described by the Technology Readiness Level (TRL) framework. Particularly, ongoing fundamental progress in membranes and engineering is expected to continue fueling the future development of these technologies.