Self-healing behavior of superhard covalent bond materials

In recent years, superhard covalently bonded materials have drawn a great deal of attention due to their excellent mechanical properties and potential applications in various fields. This review focuses on the self-healing behavior of these materials, outlining state-of-the-art research results. In detail, we discuss current self-healing mechanisms of self-healing materials including extrinsic healing mechanisms (such as microencapsulation, oxidative healing, shape memory, etc.) and intrinsic healing (dynamic covalent bonding, supramolecular interactions, diffusion, defect-driven processes, etc.). We also provide an overview of the progress in the self-healing behavior of superhard covalently bonded materials and the mechanisms of permanent covalent bonding healing. Additionally, we analyze the factors that influence the healing properties of these materials. Finally, the main findings and an outlook on the future directions and challenges of this emerging field are summarized in the Conclusion section.