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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
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Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Types Of Superconductors01:28

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A superconductor is a substance that offers zero resistance to the electric current when it drops below a critical temperature. Zero resistance is not the only interesting phenomenon as materials reach their transition temperatures. A second effect is the exclusion of magnetic fields. This is known as the Meissner effect. A light, permanent magnet placed over a superconducting sample will levitate in a stable position above the superconductor. High-speed trains that levitate on strong...
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A substance that reaches superconductivity, a state in which magnetic fields cannot penetrate, and there is no electrical resistance, is referred to as a superconductor. In 1911, Heike Kamerlingh Onnes of Leiden University, a Dutch physicist, observed a relation between the temperature and the resistance of the element mercury. The mercury sample was then cooled in liquid helium to study the linear dependence of resistance on temperature. It was observed that, as the temperature decreased, the...
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Batteries and Fuel Cells03:12

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Semiconductors01:22

Semiconductors

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There is variation in the electrical conductivity of materials - metals, semiconductors, and insulators that are showcased with the help of the energy band diagrams.
Metals such as copper (Cu), zinc (Zn), or lead (Pb) have low resistivity and feature conduction bands that are either not fully occupied or overlap with the valence band, making a bandgap non-existent. This allows electrons in the highest energy levels of the valence band to easily transition to the conduction band upon gaining...
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Band Theory02:35

Band Theory

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When two or more atoms come together to form a molecule, their atomic orbitals combine and molecular orbitals of distinct energies result. In a solid, there are a large number of atoms, and therefore a large number of atomic orbitals that may be combined into molecular orbitals. These groups of molecular orbitals are so closely placed together to form continuous regions of energies, known as the bands.
The energy difference between these bands is known as the band gap.
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Related Experiment Video

Updated: May 20, 2025

Focused Ion Beam Fabrication of LiPON-based Solid-state Lithium-ion Nanobatteries for In Situ Testing
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Surface-Conducting Lithium Superionic Conductors for Solid-State Batteries.

Bing Ai1, Wenru Zhao2, Malin Li3

  • 1State Key Laboratory of Bioinspired Interfacial Materials Science, Innovation Center for Chemical Science, College of Chemistry Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, PR China.

Journal of the American Chemical Society
|March 24, 2025
PubMed
Summary
This summary is machine-generated.

Researchers developed novel surface-conducting lithium superionic conductors via chemisorption, enhancing solid-state battery performance. This breakthrough offers lightweight, highly conductive electrolytes for advanced energy storage.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Solid-State Chemistry

Background:

  • Bulk lithium superionic conductors face limitations like grain boundary disruption and porosity, hindering energy density in solid-state batteries.
  • High densification is often required, which can compromise the gravimetric energy density of solid-state batteries.

Purpose of the Study:

  • To discover and develop a new class of surface-conducting lithium superionic conductors.
  • To overcome the limitations of bulk conductors by utilizing surface chemisorption for enhanced lithium-ion transport.
  • To create ultralight and highly conductive solid-state electrolytes for high-energy-density batteries.

Main Methods:

  • Surface chemisorption of ligands onto inert substrates (e.g., TiO2 nanosheets) to create lithium-ion binding and hopping sites.
  • Characterization of surface Li+ diffusion using electrochemical techniques.
  • Fabrication of an ultralight oxide aerogel solid-state electrolyte.
  • Assembly and testing of a LiFePO4-based solid-state battery.

Main Results:

  • Achieved a high surface ion mobility of 3.61 × 10^-7 cm^2·V^-1·s^-1 on ethylene glycolate-chemisorbed TiO2, a 600% improvement over bulk Li7La3Zr2O12.
  • Developed an ultralight oxide aerogel electrolyte with a density of 0.29 g·cm^-3.
  • Demonstrated a LiFePO4-based solid-state battery with an energy density of ~295 Wh·kg^-1, 160% higher than a Li7La3Zr2O12-based battery.
  • Showcased the generalizability of the surface-conducting design for diverse cations and substrates.

Conclusions:

  • Surface chemisorption is a viable strategy for creating novel surface-conducting lithium superionic conductors.
  • This approach enables the development of ultralight, highly conductive solid-state electrolytes.
  • The findings promise significant advancements in solid-state battery technology and other applications requiring efficient ion transport.