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Updated: May 5, 2026

A Method for Studying the Temperature Dependence of Dynamic Fracture and Fragmentation
Published on: June 28, 2015
An Advanced Heat-Resistant Explosive through Regional Isomerization and Intramolecular Integration
Chengchuang Li1, Teng Zhu1, Jie Tang1
1School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing 210094, P. R. China.
Abstract:
Among all compounds constructed by intramolecular integration, 4 (Td = 321 °C, D = 8799 m s-1, IS = 35 J) that integrates ortho amino nitro group and tetrazole framework possesses a much better comprehensive performance than most widely used heat-resistant explosive HNS (Td = 318 °C, D = 7612 m s-1, IS = 5 J), which suggest that it might be a candidate for advanced heat-resistant explosive. Compared with 8, isomer 4 shows significant improvement in density, thermal stability and sensitivity, which may be caused by the relatively strong structural aromaticity, hydrogen bond and large face-to-face π-π interaction surfaces strength.
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