Ultrafast fabrication of ε-polylysine/amide-modified chitin-based conductive hydrogel with self-healing, adhesive and...

In the realm of health monitoring, wearable electronic devices that utilize conductive hydrogels have garnered considerable attention. Nonetheless, the formidable challenge persists in streamlining the intricate preparation process and formulating a conductive hydrogel that seamlessly integrates diverse functionalities. In this study, we propose a strategy to fabricate multifunctional wearable hydrogel-based strain sensors (ε-PL/AMC-Al) in an ultrafast manner. Amide-modified chitin (AMC) was synthesized homogeneously, thereafter, Al³⁺ ions and ε-Polylysine (ε-PL) were introduced to interact with AMC through physical cross-linking techniques to form a three-dimensional network. Favorable mechanical and self-healing properties were achieved through the presence of multiple noncovalent interactions. The incorporation of ε-PL imparted antibacterial properties to the hydrogel sensor, thereby safeguarding it against bacterial contamination. Importantly, the incorporation of Al³⁺ not only facilitated the gelation process but also imparted electrical conductivity to the hydrogel, enabling it to function as a strain sensor. Notably, the adhesive property of the ε-PL/AMC-Al hydrogel ensured intimate contact, thereby allowing it to accurately monitor and differentiate between both gross and subtle human body movements without compromising its long-term stability. Based on its straightforward manufacturing process and versatility, the as-prepared hydrogel sensor exhibits significant potential for a diverse array of large-scale applications, including wearable electronic devices.