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Geology and Geomorphology Drive Polycyclic Aromatic Compound Concentrations and Composition in Rivers Draining the
Brandon R Hill1, Colin A Cooke1,2, Alberto V Reyes1
1Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta T6G 2E3, Canada.
Environmental Science & Technology
|March 27, 2025
Summary
Riverine polycyclic aromatic compounds (PACs) in Alberta are mainly from natural bitumen erosion, not mining. This study clarifies contaminant sources in watersheds impacted by oil sands operations.
Area of Science:
- Environmental Chemistry
- Geochemistry
- Ecotoxicology
Background:
- Large-scale open-pit bitumen mining in Alberta raises concerns about polycyclic aromatic compounds (PACs) contamination.
- Bitumen-rich McMurray Formation erosion complicates distinguishing natural from industrial PAC sources in rivers.
Purpose of the Study:
- Quantify PAC concentrations, loads, and yields in rivers draining mining-impacted watersheds.
- Differentiate between natural and anthropogenic PAC inputs in riverine systems.
- Identify primary drivers of PAC transport in affected watersheds.
Main Methods:
- Collected 998 water quality samples upstream and downstream of mining operations.
- Analyzed samples for 48 unsubstituted and alkylated PAC homologues.
- Compared PAC compositional fingerprints to potential natural and industrial sources.
Main Results:
- PAC input and riverine transport are primarily driven by erosion of bituminous outcrops.
- Watershed PAC loads and yields varied with industrial development and outcrop distribution.
- PAC relative abundances shifted, indicating natural sources dominate.
Conclusions:
- Eroding bitumen-rich outcrops, not industrial pollution, are the main source of riverine PACs.
- PAC concentrations are controlled by outcrop presence and river hydrography.
- Study clarifies contaminant sources in bitumen-mining impacted ecosystems.
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