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Halogen-Driven Spin Dynamics: Exploring Correlation of Cooperativity and Spin Crossover in Solid-State Mononuclear

Li-Wen Chen1, Hai Zhu1, Hua-Wei Zhou1

  • 1State Key Laboratory of Flexible Electronics (LoFE) & Institute of Advanced Materials (IAM), Nanjing University of Posts & Telecommunications, 9 Wenyuan Road, Nanjing 210023, China.

Inorganic Chemistry
|March 28, 2025
PubMed
Summary

We synthesized four new iron(III) complexes with halogen-substituted ligands. Complex 2 shows a unique two-step spin crossover, demonstrating how halogens influence magnetic properties in spin crossover (SCO) materials.

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