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Updated: Jun 16, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Exploring the Nuclearity and Structural Motifs of Phenoxyimine Alkaline Earth Complexes
Amy V Rizzo1, Rebecca L Jones1, Matthew D Haynes1
1Chemistry Research Laboratory, Department of Chemistry, University of Oxford, Mansfield Road, Oxford OX1 3TA, U.K.
Abstract:
The nuclearity and structural motifs of alkaline earth complexes supported by bidentate phenoxyimine ligands has been explored by modulation of the stereoelectronic profile of the ligand, the atomic number of the metal, and the synthetic protocol. Changing the size of the N-imine substituents was found to have no effect on protonolysis reactions between [MgN″2]2 or CaN″2(thf)2 (N″ = N(SiMe3)2) and H L (1-OH-2-CH = NAr-4,6- Bu-C6H2; Ar = 2,6-iPr-C6H3 = Dipp or 2,6-CHPh2-4-Me-C6H2 = Ar*) regardless of reaction stoichiometry, with homoleptic bis(ligand) complexes ( L)2Mg (1), ( L)2Mg (2), ( L)2Ca(thf) (3) and ( L)2Ca(thf) (4) isolated. The importance of reaction protocol was demonstrated by the facile isolation of heteroleptic complex ( L)MgI(OEt2) (5) from the reaction of equimolar amounts of H L and MeMgI. Importantly, no subsequent ligand redistribution was observed when complex 5 readily reacted with KN" or KODipp to form ( L)Mg{N(SiMe3)2}(OEt2) (6) and ( L)Mg(ODipp)(thf) (7). When small 4,6-phenoxide substituents were considered (HHL), multimetallic clusters were afforded: (HL)3Ca2(N″)(thf) (8) and (HL)6Sr3 (9).
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