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Published on: March 20, 2014
Reactivity of an arsanyl-phosphagallene: decarbonylation of CO2 and COS to form phosphaketenes
Lilian S Szych1,2, Jonas Bresien3, Lukas Fischer2
1Department of Chemistry, University of Oxford, Chemistry Research Laboratory 12 Mansfield Road Oxford OX1 3TA UK.
Abstract:
The synthesis of an arsanyl-phosphagallene [H2CN(Dipp)]2AsP[double bond, length as m-dash]Ga(NacNac) (NacNac = HC[C(Me)N(Dipp)]2; Dipp = diisopropylphenyl) and its reactivity towards heterocumulenes and ketones is described. Reactions with azides, carbodiimides, isocyanates and ketones give rise to heterocycles via cyclization reactions involving the Ga[double bond, length as m-dash]P π-bond (with the Ga-P σ-bond remaining unperturbed in the final products). By contrast, reactions with CO2, CS2 and COS are more intriguing, revealing a reactivity profile in which the phosphorus atom can abstract carbon monoxide from the oxygen-containing heterocumulenes. These reactions result in the formation of gallium phosphaethynolate compounds. Such reactivity is enabled by the presence of a weakly Lewis basic arsanyl moiety which, in contrast to other related compounds featuring phosphanyl groups, is insufficiently nucleophilic to play a role in frustrated Lewis-pair like reactivity.
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