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Updated: Jun 23, 2026

The Effect of Ultraviolet Radiation on the Chemical Bath Deposition of Bis(thiourea) Cadmium Chloride Crystals and the Subsequent CdS Obtention
Published on: August 30, 2018
Bulkiness effect dependent photosalient behaviours of photoactive cadmium coordination polymers
Qing-Shu Dong1, Ning Wang1, David James Young2
1Key Laboratory of Chemistry and Engineering of Forest Products, State Ethnic Affairs Commission, Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi Collaborative Innovation Center for Chemistry and Engineering of Forest Products, Guangxi Minzu University, Nanning 530006, China. hflphd@163.com.
Abstract:
Three structurally related cadmium coordination polymers CP1-CP3 {[Cd3(Pebpeb)2(L1)6] (CP1), [Cd3(Pebpeb)2(L2)6] (CP2) and [Cd6(Pebpeb)4(L3)12]·HL3 (CP3)} were constructed from the photoactive alkene ligand Pebpeb (Pebpeb = 4,4'-((1E,1'E)-(5-(pyridin-3-ylethynyl)-1,3-phenylene)bis(ethene-2,1-diyl))dipyridine; HL1 = 3-chlorobenzoic acid; HL2 = 3-nitrobenzoic acid; HL3 = 3-isopropyl benzoic acid) and Cd(II) ions in the presence of different auxiliary carboxylic acids. Different conformations of the functional olefinic ligand Pebpeb were observed in CP1-CP3 despite their similar 1D chain motif. [2 + 2] Solid-state photodimerization occurred when crystals of CP1-CP3 were irradiated with UV light (365 nm) and each displayed different photosalient (PS) responses attributed to the different bulkiness of the auxiliary carboxylic acids employed. A simple photoactuating device was prepared using a CP1-PVA (PVA = Polyvinyl Alcohol) composite.
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