Understanding the Current Distribution and Mass Transport Properties in 3D-Printed Architected Flow-Through...

Architected materials offer promising advancements in energy storage by enabling highly customizable, high-surface-area, ordered, and low-defect porous structures. This study investigates the current distribution and mass transport within complex 3D-printed lattice electrodes under flow-through conditions. Conductive lattices were fabricated using microstereolithography followed by pyrolytic carbonization. Lattice geometry effects were analyzed by varying the unit cell type [simple cubic (SC), body- and face-centered cubic (BCC/FCC), IsoTruss, and Octet], porosity, and current density. Current distribution uniformity was investigated using a model high-efficiency copper deposition reaction. Local film thickness distributions were predicted using a numerical model and validated experimentally using micro-X-ray computed tomography. Scaling relationships for informing electrochemical reaction conditions and current uniformity are formulated as a modified lattice-based Wagner number (Wa _Lattice) and a corresponding inverse Damkohler number (Da _Lattice ^-1). Validated models reveal that mass-transfer coefficients scale as Octet > IsoTruss > FCC ∼ BCC > SC. Inertial effects become significant at Reynolds number Re > 3 and are particularly pronounced in Octet structures due to an abundance of struts oriented away from the fluid flow direction. The study underscores the importance of electrode engineering and process conditions necessary to tailor mass transport and current uniformities to various device applications.