Carboxymethyl cellulose/alginate/chitosan-based polyelectrolyte complex hydrogel with irregularly shaped...

The efficient removal of hexavalent chromium (Cr(VI)) from industrial wastewater is a pressing environmental challenge. A natural polyelectrolyte complex (PEC) hydrogel composed of carboxymethyl cellulose, alginate and chitosan, was developed to support Pd/Au/Ag/Pt nanowires for the continuous-flow catalytic reduction of Cr(VI) to the less toxic Cr(III). PEC hydrogels are formed through the association of oppositely charged polyelectrolytes, a process that is primarily driven by entropy gain due to the release of counterions, resulting in highly porous networks with tunable physical and chemical properties. These characteristics make them ideal platforms for nanoparticle stabilization and catalytic applications. Crosslinking with glutaraldehyde, citric acid and calcium ions further improved the stability and porosity of the hydrogels. Pd/Au/Ag/Pt nanowires, synthesised through galvanic replacement and co-reduction of Pd/Au/Ag nanowires formed via an oriented attachment mechanism, exhibit a distinctive, irregular, undulating morphology that enhances their suitability for introduction into hydrogel matrices. These multi-metallic nanowires achieved complete Cr(VI) reduction within 15 min. When incorporated into a nanocomposite hydrogel, the Pd/Au/Ag/Pt nanowires significantly enhanced catalytic activity while maintaining structural integrity and high catalytic efficiency. Notably, the system achieved complete Cr(VI) reduction within 5 h of continuous-flow operation, highlighting its potential as a robust and scalable solution for industrial wastewater remediation.