Related Experiment Video
Updated: May 15, 2025

High-Contrast and Fast Photorheological Switching of a Twist-Bend Nematic Liquid Crystal
Published on: October 31, 2019
Thermodynamic signatures of diagonal nematicity in RbFe2As2 superconductor
Yuta Mizukami1,2, Ohei Tanaka1, Kousuke Ishida1
1Department of Advanced Materials Science, University of Tokyo, Kashiwa, Chiba 277-8561, Japan.
This study provides thermodynamic evidence for diagonal nematicity in iron-based superconductors using heat capacity measurements. The findings suggest a charge-driven mechanism for this unique electronic nematic state.
Area of Science:
- Condensed Matter Physics
- Materials Science
- Superconductivity
Background:
- Electronic nematic states break rotational symmetry in correlated materials.
- Iron-based superconductors typically exhibit nematicity aligned with the Fe-Fe lattice direction.
- A unique diagonal nematicity along the Fe-As direction has been proposed for heavily hole-doped ( or Cs).
Purpose of the Study:
- To investigate the presence and orientation of nematic fluctuations in using thermodynamic measurements.
- To clarify conflicting outcomes from previous transport studies on diagonal nematicity.
- To elucidate the mechanism and thermodynamic properties of the diagonal nematic transition.
Main Methods:
- High-resolution heat capacity measurements with in-plane magnetic field rotation.
- Analysis of field-angle dependence of specific heat near the superconducting transition.
- Mössbauer spectroscopy to probe the nematic transition and magnetic ordering.
Main Results:
- No anomaly in specific heat's temperature dependence indicated a nematic transition.
- Field-angle dependence revealed clear 2-fold oscillations, providing thermodynamic evidence for diagonal nematicity.
- Mössbauer spectroscopy detected the nematic transition at K without static magnetism.
Conclusions:
- Diagonal nematicity in is thermodynamically confirmed.
- The nematicity likely arises from charge degrees of freedom, not static magnetism.
- This suggests an unusual mechanism for the nematic transition in this material.
Related Concept Videos
Thermal Sigmatropic Reactions: Overview
Sigmatropic shifts are classified based on an order term [i, j ], where i and j indicate the number of atoms across which each end of the σ bond migrates. Below are examples of a [3,3] sigmatropic shift in...
¹H NMR of Conformationally Flexible Molecules: Variable-Temperature NMR
¹H NMR of Conformationally Flexible Molecules: Temporal Resolution
π Electron Effects on Chemical Shift: Aromatic and Antiaromatic Compounds
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations
Diamagnetic Shielding of Nuclei: Local Diamagnetic Current

