Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

The feasibility and analysis of 2D bilayer SiC as an alcohol sensor: a first-principle study.

Journal of molecular modeling·2026
Same author

Water Microdroplets Induce Heterocyclic Transmutation: Skeletal Editing of Aniline into Pyridine at the Air-Water Interface.

Journal of the American Chemical Society·2026
Same author

Occupational exposure to respirable crystalline silica and its association with pulmonary function impairment among coal mine workers: A retrospective assessment.

Environmental research·2026
Same author

Synergistic Regulation of Excited-State Electrons Enables Sunlight-Driven C─Br Bond Activation Through In Situ Polymerized Polyoxometalate-Gold Nanocluster Assemblies.

Small (Weinheim an der Bergstrasse, Germany)·2026
Same author

SPNS2 exports sphingosine-1-phosphate and imports glucose.

Nature communications·2026
Same author

Exposure assessment of respirable free silica in coal mining areas.

Environmental geochemistry and health·2026
Same journal

A Domino-Synthesized Dicoordinate Copper(I) Bis-imidazopyridine Complex Triggering Cuproptosis/Ferroptosis for Enhanced Cancer Immunotherapy.

Angewandte Chemie (International ed. in English)·2026
Same journal

Mirror-Symmetric Organic Two-Dimensional Crystals for Alternative Photon Transport Pathways.

Angewandte Chemie (International ed. in English)·2026
Same journal

Cobalt-Catalyzed Migratory E-Selective Asymmetric Aza-Nozaki-Hiyama-Kishi Coupling.

Angewandte Chemie (International ed. in English)·2026
Same journal

Facile Synthesis of α,ω-Dihydroxy Telechelic Macromonomers From Ethylene and α-Olefins for Recyclable Alternating Block Copolymers.

Angewandte Chemie (International ed. in English)·2026
Same journal

Multi-Atom Sub-Nanometer Assemblies on Interpenetrating Multi-Chambered N/C Nanospheres.

Angewandte Chemie (International ed. in English)·2026
Same journal

A Synergistic C<sub>2+</sub> Alcohols/Olefins-Intermediated Pathway Boosts CO<sub>2</sub> Hydrogenation to Aromatics.

Angewandte Chemie (International ed. in English)·2026
See all related articles

Related Experiment Video

Updated: May 15, 2025

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

1.5K

Sprayed Microdroplets Architect a Polyoxometalate Framework.

Abhijit Nandy1, Gajiram Murmu2, Anitesh Rana1

  • 1Department of Chemistry, Indian Institute of Science Education and Research Tirupati, Tirupati, 517619, India.

Angewandte Chemie (International Ed. in English)
|April 8, 2025
PubMed
Summary
This summary is machine-generated.

Synthesizing tungsten-based polyoxometalates (POMs) is now possible in microdroplets. This novel method offers a greener, faster alternative for producing these valuable inorganic compounds.

Keywords:
Air–liquid interfaceMicrodroplet chemistryPolyoxometalateRapid nucleationUnusual reaction

More Related Videos

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.0K
Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
10:27

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

Published on: July 14, 2015

10.0K

Related Experiment Videos

Last Updated: May 15, 2025

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites
06:48

Author Spotlight: Exploring Self-Assembled MOF-Polymer Composites

Published on: June 14, 2024

1.5K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.0K
Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides
10:27

Preparation of Highly Porous Coordination Polymer Coatings on Macroporous Polymer Monoliths for Enhanced Enrichment of Phosphopeptides

Published on: July 14, 2015

10.0K

Area of Science:

  • Inorganic Chemistry
  • Materials Science
  • Nanotechnology

Background:

  • Micron-sized droplets have been explored for organic reactions.
  • Their application in inorganic bond formation, particularly for polyoxometalates (POMs), is underexplored.
  • Traditional POM synthesis often requires harsh chemicals and conditions.

Purpose of the Study:

  • To develop a novel, efficient method for synthesizing tungsten-based Lindqvist-type polyoxometalates (POMs).
  • To explore the use of microdroplets for inorganic synthesis under ambient conditions.
  • To elucidate the mechanism of POM formation in microdroplets.

Main Methods:

  • Aerosolization of a simple tungstate (WO4^2-) solution in various organic and aqueous microdroplets.
  • Ambient condition synthesis.
  • Mass spectrometry for reactive intermediate detection.
  • X-ray crystallography for characterization.

Main Results:

  • Spontaneous formation of a tungsten-based Lindqvist-type POM (W6O19^2-) achieved.
  • High yields (up to 99%) obtained in less than a millisecond.
  • Mechanism of nucleation and growth in microdroplets elucidated.
  • Successful characterization of the synthesized POM.

Conclusions:

  • Microdroplets provide a viable and efficient platform for synthesizing POMs.
  • This method avoids hazardous chemicals and high-boiling solvents, offering a greener approach.
  • Rapid solvent evaporation and reactant enrichment in microdroplets drive POM formation.