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Updated: May 15, 2025
Construction and Systematical Symmetric Studies of a Series of Supramolecular Clusters with Binary or Ternary Ammonium Triphenylacetates
Published on: February 15, 2016
Crystal structure and Hirshfeld surface analyses, inter-molecular inter-action energies and energy frameworks of
Farid N Naghiyev1, Tuncer Hökelek2, Victor N Khrustalev3,4
1Department of Chemistry, Baku State University, Z. Khalilov Str. 23, Az 1148 Baku, Azerbaijan.
Abstract:
The title compound, C17H15N3O7, contains pyran and phenyl rings, with the pyran ring exhibiting a flattened-boat conformation. In the crystal, inter-molecular N-H⋯N hydrogen bonds link the mol-ecules into centrosymmetric dimers, forming R 2 2(12) ring motifs. These dimers are linked through N-H⋯O hydrogen bonds into a three-dimensional architecture. A Hirshfeld surface analysis indicates that the most important contributions for the crystal packing are from H⋯O/O⋯H (29.7%), H⋯H (28.7%), H⋯C/C⋯H (16.0%) and H⋯N/N⋯H (12.9%) inter-actions. In addition to van der Waals inter-actions and N-H⋯N and N-H⋯O hydrogen bonds, halogen bonds, tetrel bonds and pnictogen bonds also play an important role in the cohesion of the crystal structure.
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