Exploring the Potential of SnHPO₃ and Ni_3.4Sn₄ as Anode Materials in Argyrodite-Based All-Solid-State Lithium-Ion...

All-solid-state batteries have garnered significant attention due to their potential to exceed the energy density of conventional lithium-ion batteries, particularly when alloying-based materials or lithium metal anodes are used. However, achieving compatibility with lithium metal remains a persistent bottleneck. In this study, we shed light on the potential of SnHPO₃ tin phosphite and Ni_3.4Sn₄ intermetallic as novel conversion/alloying anode materials for all-solid-state lithium batteries using Li₆PS₅Cl as the solid electrolyte. The two Sn-based active materials were nanostructured by ball-milling to demonstrate considerable promise for application in all-solid-state half-cells. Galvanostatic cycling at room temperature revealed electrochemical behavior based on conversion/alloying reactions akin to those observed in conventional lithium-ion batteries. Promisingly, both materials exhibited satisfying electrochemical stability, with coulombic efficiencies exceeding 97%. These findings indicate that Li₆PS₅Cl solid electrolyte is compatible with Sn-based alloying anodes.