Advancing agricultural efficiency and sustainability: Bio-inspired superabsorbent hydrogels for slow and controlled...

Bio-inspired superabsorbent hydrogels (BiSAHs) represent a versatile polymeric material class that has garnered significant interest due to their multifunctional attributes and extensive range of applications. A thorough examination of the literature and patents on BiSAHs highlights their critical role across diverse sectors. This review provides an in-depth analysis of BiSAHs, focusing on their classification, synthesis methodologies, and potential applications in agriculture. It critically examines biopolymer-based SAHs as soil conditioners and slow and controlled, focusing on their classification, synthesis methodologies, and potential applications in agriculture. It critically examines biopolymer-based SAHs as soil conditioners and slow and controlled-release fertilizers, elucidating the mechanisms governing water retention, swelling capacity, and nutrient release kinetics. The review further presents detailed case studies illustrating the enhancement of crop growth and productivity facilitated by BiSAHs and their effectiveness as agrochemical carriers. Moreover, it explores the role of SAHs in crop protection, particularly in mitigating adverse abiotic stresses such as heavy metal toxicity, salinity, and drought. The ecological, economic, and societal impacts of BiSAH-based controlled-release fertilizers are evaluated, providing a balanced perspective on their sustainability. Ultimately, the review offers insights into future directions and emerging advancements in the development and application of BiSAHs in agricultural settings.