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Related Concept Videos

IR Frequency Region: Fingerprint Region01:03

IR Frequency Region: Fingerprint Region

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IR spectra are divided into two main regions: the diagnostic region and the fingerprint region. The diagnostic region of the spectrum lies above 1500 cm−1. The absorptions resulting from single-bond vibrations of the N–H, C–H, and O–H stretch at higher wavenumbers and appear on the left side of the spectrum. The stretching absorptions of the C≡C and C≡N occur between 2100–2300 cm−1. In contrast, those arising from stretching absorptions of the...
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Attenuated Total Reflectance (ATR) Infrared Spectroscopy: Overview01:13

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Attenuated total reflectance (ATR) infrared spectroscopy is a powerful analytical technique used to study the composition of materials. It is widely employed in chemistry, materials science, forensic science, and other fields where sample characterization is required. ATR has several advantages over traditional transmission IR spectroscopy, including the requirement of little to no sample preparation and the ability to analyze a wide range of samples.
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Aromatic compounds can be identified or analyzed using proton NMR and carbon‐13 NMR. Typically, aromatic hydrogens or hydrogens directly bonded to the aromatic rings are strongly deshielded by the aromatic ring current. Therefore, they absorb in the range of 6.5–8.0 ppm in proton NMR spectra. For instance, aromatic hydrogens directly bonded to the benzene ring absorb at 7.3 ppm. However, aromatic hydrogens of larger rings absorb farther upfield or downfield than the ideal range.
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¹³C NMR: ¹H–¹³C Decoupling01:04

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The probability of having two carbon-13 atoms next to each other is negligible because of the low natural abundance of carbon-13. Consequently, peak splitting due to carbon-carbon spin-spin coupling is not observed in spectra. However, protons up to three sigma bonds away split the carbon signal according to the n+1 rule, resulting in complicated spectra.
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2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)01:19

2D NMR: Heteronuclear Single-Quantum Correlation Spectroscopy (HSQC)

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Heteronuclear single-quantum correlation spectroscopy (HSQC) is a 2D NMR technique that reveals one-bond correlations between hydrogen and a heteronucleus. The HSQC experiment is similar to the heteronuclear correlation experiment (HETCOR) but is more sensitive. In the HSQC spectrum, the proton chemical shift is plotted on the horizontal F2 axis, while the 13C chemical shift is plotted on the vertical F1 axis. The corresponding proton and 13C spectra are also shown. The HSQC contour plot does...
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Coffee Bean Characterization Using Terahertz Sensing.

Dook van Mechelen1, Daan Meulendijks1, Milan Koumans1

  • 1Department of Electrical Engineering, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands.

Sensors (Basel, Switzerland)
|April 12, 2025
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Summary
This summary is machine-generated.

This study introduces terahertz (THz) spectroscopy for sorting coffee beans by internal moisture. This novel method offers a more accurate approach than visual inspection for optimizing the roasting process.

Keywords:
THz spectroscopycoffee bean sortingmoisture level of coffee beansoptical properties of coffee beans

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Area of Science:

  • Agricultural Science
  • Spectroscopy
  • Food Science

Background:

  • Current coffee bean sorting relies on visual inspection and near-infrared (NIR) spectroscopy, which primarily analyze the bean's surface.
  • Sorting based on internal composition, such as moisture content, holds significant potential for optimizing coffee roasting.
  • Existing methods lack the ability to effectively probe the internal properties of coffee beans non-destructively.

Purpose of the Study:

  • To develop and demonstrate a novel coffee bean sorting method utilizing terahertz (THz) spectroscopy.
  • To investigate the correlation between THz optical properties and internal moisture levels in coffee beans.
  • To assess the industrial feasibility of THz spectroscopy for automated coffee bean sorting.

Main Methods:

  • Terahertz (THz) spectroscopy was employed to analyze both green and roasted coffee beans.
  • A robot-guided THz sensing system was developed for automated scanning of bean beds.
  • The relationship between THz optical properties and internal moisture content was investigated.

Main Results:

  • Terahertz (THz) spectroscopy effectively penetrates coffee beans, providing insights into internal properties.
  • The optical properties of coffee beans at THz frequencies are strongly correlated with internal moisture levels.
  • The implemented robot-guided THz system demonstrated industrial feasibility for automated sorting.

Conclusions:

  • Terahertz (THz) spectroscopy offers a novel and effective method for sorting coffee beans based on internal moisture content.
  • This technology has the potential to significantly optimize the coffee roasting process by enabling composition-based sorting.
  • The findings confirm the broader applicability of THz technology for non-destructive moisture content analysis in various materials.