Enhanced remediation of diesel-contaminated soils using a novel biopolymer-based emulsion

Conventional in-situ light non-aqueous phase liquid (LNAPL) remediation techniques often face challenges of high costs and limited efficiency, leaving residual hydrocarbons trapped in soil pores. This study investigates the efficiency of an alcohol-in-biopolymer emulsion for enhancing diesel-contaminated soil remediation. The emulsion, formulated with xanthan gum biopolymer, sodium dodecyl sulfate surfactant, and the oil-soluble alcohol 1-pentanol, was evaluated through rheological tests, interfacial tension measurements, and one-dimensional sand-column experiments under direct injection and post-waterflooding scenarios. The emulsion exhibited non-Newtonian shear-thinning behavior with high viscosity, ensuring stable propagation and efficient delivery of 1-pentanol to mobilize trapped diesel ganglia. It achieved 100 % diesel recovery within 1.2 PV during direct injection, outperforming shear-thinning polymer-only and polymer-surfactant solutions, which achieved recovery factors of 83.4-92.9 %. Post-waterflooding experiments also demonstrated 100 % diesel recovery within 1.3 PV, regardless of initial diesel saturation. Key mechanisms include reduced interfacial tension, diesel swelling and mobilization induced by 1-pentanol, and uniform displacement facilitated by the emulsion's viscosity. Additionally, the emulsion required lower injection pressures compared to more viscous alternatives, enhancing its injectability into the soil and reducing energy demands. These findings highlight the emulsion's potential to overcome conventional remediation limitations, offering a highly effective and sustainable solution for diesel-contaminated soils and groundwater.