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Construction of an organic cage-based porous ionic liquid using an aminal tying strategy
Aiting Kai1, Austin Mroz2,3, Kim E Jelfs2
1Department of Chemistry and Materials Innovation Factory, University of Liverpool 51 Oxford Street Liverpool L7 3NY UK.
Abstract:
An aminal tying method was applied to post-synthetically modify a flexible organic cage, RCC1, to construct a porous ionic liquid (PIL). The resulting PIL, [RCC1-IM][NTf2]6, displayed melting behaviour below 100 °C, a transition to a glass phase on melt-quenching, CO2 uptake, and its permanent porosity was confirmed using molecular dynamic simulations.

