Engineered covalent organic frameworks (COFs) for adsorption-based metal separation technologies: A critical review

Porous covalent organic frameworks (COFs) are promising materials used for separation and purification during environmental remediation. This critical review focuses on two key aspects. First, it critically examines strategies to improve COF design and structure and evaluates their impact on separation performance. Second, engineering approaches for enhancing the interactions between COF-based adsorbents and metals for enhanced separation and capture are elucidated. The latest body of research on separating metals (e.g., Li, K, Sr, Hg, Cd, Pb, Cr, Au, Ag, Pd, and U) using COF-based adsorbents is discussed to understand the factors that influence their performance. However, it is to be noted that COF-based adsorbents are still in their infancy and remain largley unexplored, mainly hindered by synthetic complexities and suboptimal crystalline structures. This highlights the need for further research and development to fully unlock the excellent potential of COFs for metal separation applications, particularly in environmental and energy applications.