Immobilization of lead and zinc in contaminated soil using taro stem-derived biochar and apatite amendments: a comparative study of application ratios and pyrolysis temperatures

  • 0Faculty of Chemistry, TNU-University of Science Tan Thinh Ward Thai Nguyen City 24000 Vietnam xuanvt@tnusedu.vn.

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Summary

This summary is machine-generated.

Taro stem biochar and apatite effectively immobilize lead and zinc in contaminated soil. Amendments increased soil pH and organic carbon, reducing toxic metal mobility for environmental remediation.

Area Of Science

  • Environmental Science
  • Soil Science
  • Geochemistry

Background

  • Soil contamination by heavy metals like lead (Pb) and zinc (Zn) poses significant environmental risks.
  • Biochar and apatite are recognized for their potential in soil remediation.
  • The combined efficacy of different biochar types and apatite for heavy metal immobilization requires further investigation.

Purpose Of The Study

  • To evaluate the effectiveness of taro stem-derived biochar (TSB) produced at different temperatures (300 °C and 500 °C) and apatite in immobilizing Pb and Zn in contaminated soil.
  • To determine the optimal amendment ratios for heavy metal immobilization.
  • To assess the impact of amendments on soil properties such as pH, organic carbon (OC), and electrical conductivity (EC).

Main Methods

  • Incubation of contaminated soil with TSB300, TSB500, and apatite at various ratios (3%, 6%, 10% biochar; 3:3% and 6:6% biochar-apatite mixtures) for one month.
  • Analysis of Pb and Zn concentrations in five chemical fractions (exchangeable, carbonate, Fe/Mn oxide, organic carbon, residual) using Tessier's sequential extraction.
  • Measurement of soil pH, OC, and EC.

Main Results

  • Amendments significantly increased soil pH, OC, and EC compared to the control.
  • Exchangeable fractions (F1) of Pb and Zn were reduced by up to 71.8% and 61.5%, respectively.
  • Pb and Zn were effectively immobilized, with peak reduction observed at 10% TSB and 6:6% TSB-apatite mixture, enhancing their presence in stable fractions (F4 and F5).

Conclusions

  • Taro stem-derived biochar (TSB300, TSB500) and its blends with apatite are effective in immobilizing Pb and Zn in heavily contaminated soils.
  • These amendments improve soil physicochemical properties, contributing to metal stabilization.
  • The study highlights the potential of TSB and apatite as sustainable solutions for mitigating heavy metal pollution in soils.