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Published on: November 26, 2014
Redox mediated dimerisation of a cyclo-As8 complex
Christoph Riesinger1, Manfred Scheer1
1Institute of Inorganic Chemistry, University of Regensburg Universit ä tsstr 31 93053 Regensburg Germany manfred.scheer@chemie.uni-regensburg.de.
Abstract:
Reduction as well as oxidation of the cyclo-As8 complex [{Cp''Ta}2(μ,η2:2:2:2:1:1-As8)] (A, Cp'' = 1,3- Bu2C5H3) are demonstrated to afford controlled dimerisation to unprecedented As16 species. The dication [{Cp''Ta}4(μ4,η2:2:2:2:2:2:2:2:1:1:1:1-As16)]2+ slowly disproportionates in solution, yielding the largest polyarsenide species in a molecular complex known to date.
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