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Ergodicity breaking in well-behaved generalized Langevin equations.

Giuseppe Procopio1, Chiara Pezzotti1, Massimiliano Giona1

  • 1Sapienza Università di Roma, Dipartimento di Ingegneria Chimica, Materiali, Ambiente La , Via Eudossiana 18, 00184 Roma, Italy.

Physical Review. E
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Ergodicity breaking in Generalized Langevin Equations (GLEs) is explained by dissipative stability and stochastic realizability boundaries. This phenomenon is absent in viscoelastic fluids if Kubo's fluctuation-dissipation theory holds.

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Area of Science:

  • Statistical Mechanics
  • Rheology
  • Non-equilibrium Physics

Background:

  • Generalized Langevin Equations (GLEs) are crucial for modeling complex systems with memory effects.
  • Ergodicity breaking is a significant phenomenon observed in certain physical systems, challenging standard statistical mechanics assumptions.
  • The Plyukhin model and viscoelastic fluid rheology present distinct cases for studying ergodicity breaking.

Purpose of the Study:

  • To explain the phenomenon of ergodicity breaking in GLEs using the concepts of dissipative stability and stochastic realizability.
  • To investigate the conditions under which ergodicity breaking occurs or is prevented in systems with nonvanishing friction factors.
  • To provide a physical interpretation of ergodicity breaking in the context of hydromechanic theories and fluid-inertial effects.

Main Methods:

  • Application of dissipative stability and stochastic realizability concepts to analyze GLEs.
  • Examination of the Plyukhin model with a generalized Debye kernel.
  • Analysis of systems with dissipative kernels characterized by real-valued relaxation rates (viscoelastic fluids).
  • Consideration of Kubo's fluctuation-dissipation theorem.

Main Results:

  • Ergodicity breaking in GLEs occurs at the boundary of dissipative stability, coinciding with stochastic realizability for models like the Plyukhin model.
  • In viscoelastic fluids, where stochastic realizability is within dissipative stability, ergodicity breaking is precluded if Kubo's theory holds.
  • A hydromechanic interpretation attributes ergodicity breaking to a dissipationless fluid-inertial effect, leading to superdiffusion.

Conclusions:

  • Dissipative stability and stochastic realizability provide a framework for understanding ergodicity breaking in GLEs.
  • The rheological properties of the medium significantly influence the occurrence of ergodicity breaking.
  • A fluid-inertial effect offers a physical explanation for superdiffusion observed in certain ergodicity-breaking scenarios.