Low-dimensional materials for ammonia synthesis

Ammonia is an essential chemical due to its immense usage in agriculture, energy storage, and transportation. The synthesis of "green" ammonia via carbon-free routes and renewable energy sources is the need of the hour. In this context, photo- and/or electrocatalysis proves to be highly crucial. Low-dimensional materials (LDMs), owing to their unique properties, play a significant role in catalysis. This review presents a vast library of LDMs and broadly categorizes their catalytic performance according to their dimensionality, i.e., zero-, one-, and two-dimensional catalysts. The rational design of LDMs can significantly improve their catalytic performance, particularly in reducing small molecules like dinitrogen, nitrates, nitrites, and nitric oxides to synthesize ammonia via photo- and/or electrocatalysis. Additionally, converting nitrates and nitrites to ammonia can be beneficial in wastewater treatment and be coupled with CO₂ co-reduction or oxidative reactions to produce urea and other valuable chemicals, which are also discussed in this review. This review collates the works published in recent years in this field and offers some fresh perspectives on ammonia synthesis. Through this review, we aim to provide a comprehensive insight into the catalytic properties of the LDMs, which are expected to enhance the efficiency of ammonia production and promote the synthesis of value-added products.