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Updated: May 14, 2025
Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
A mixed-linker strategy in covalent organic frameworks for enhanced sunlight-driven photocatalytic oxidation activity
Jikuan Qiu1, Xinchun Xue1, Kangna Zhang1
1Collaborative Innovation Center of Henan Province for Green Manufacturing of Fine Chemicals, School of Chemistry and Chemical Engineering, Key Laboratory of Green Chemical Media and Reactions, Ministry of Education, Henan Normal University, Xinxiang, Henan 453007, P. R. China. qiujikuan@htu.edu.cn.
Abstract:
We present a simple mixed-linker strategy to enhance the photocatalytic oxidation activity and stability of covalent organic framework semiconductors. The TpTfbPa-COF, featuring an unconventional reversed AA-stacking structure with both imine and ketoamine linkages, exhibits excellent structural stability and superior photocatalytic performance compared to the fully imine-linked TfbPa-COF and the fully ketoamine-linked TpPa-COF.
