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Updated: May 10, 2025

Application of a Coupling Agent to Improve the Dielectric Properties of Polymer-Based Nanocomposites
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Unveiling Synergistic Interface Effects on Charge Trapping Regulation in Polymer Composite Dielectrics through

Haoxiang Zhao1,2,3, Lixuan An4, Daning Zhang1

  • 1State Key Laboratory of Electrical Insulation and Power Equipment, School of Electrical Engineering, Xi'an Jiaotong University, Xi'an 710049, China.

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Summary

This study introduces a new theoretical framework for polymer dielectrics, revealing how interface design can improve dielectric strength by controlling charge transport through molecular interactions and morphology. This offers new paths for advanced energy materials.

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Area of Science:

  • Materials Science
  • Polymer Science
  • Computational Chemistry

Background:

  • Interface design is crucial for enhancing dielectric strength in polymer composites by regulating charge transport.
  • Current understanding of interface mechanisms is limited, hindering targeted design due to complexities in electronic processes and morphology.

Purpose of the Study:

  • To develop a theoretical framework for polymer dielectrics based on charge hopping and multiscale modeling.
  • To elucidate the molecular origins of interface effects on charge transport and dielectric properties.

Main Methods:

  • A multiscale modeling approach was employed, linking quantum properties of charge carriers with nano- and mesoscale structural details.
  • The charge hopping model was applied to a cellulose-oil interface system.

Main Results:

  • Charges are trapped in the disordered region of the cellulose-oil interface.
  • Dual-interface regulation mechanisms were identified: energetic factors suppress back-transfer, and low electronic coupling suppresses forward-transfer.

Conclusions:

  • The study provides fundamental insights into molecular origins of interface effects in polymer dielectrics.
  • This work offers new development pathways for advanced energy materials with tailored electrical properties through dual-interface regulation.